Ateneo - UPO

Study of the chemical equilibria in solution and the volumetric determinations. Some practical experiences in laboratory.

Available material, Skoog-Leary - Chimica Analitica Strumentale - EDISES

Provide the notions on chemical equilibria in solution, qualitative and quantitative chemistry procedures. To enable students to perform the analytical methods of qualitative/quantitative analysis in the laboratory and provide them with the fundamental concepts for good laboratory practice.

None

In class lessons, laboratory experiences

The knowledge is evaluated by classroom exercises.

chemical equilibria. Written test consisting in 5 or 6 exercises about the chemical equilibria in solution (acid-base, buffers, solubility, complexes, redox, competitive equilibria)

Equilibria in solution (acid-base, complexes, precipitation, redox); activity coefficient; volumetric determinations (titration curves, indicator systems, important titrations).
Quantitative methods: method validation, representation of the results (average, standard deviation, confidence interval and Statistical hypothesis testing), critical level, LOD, LOQ, calibration curve, internal standard method, standard addition method, single addition method.
Laboratory
ectures: brief introduction to laboratory experiences.
Individual and/or group laboratory exercises include:
• titration of copper by complexometric route
• determination of copper and zinc in one of its most common alloys: comparison of the results obtained by determination in UV-Vis spectrophotometry and titration.

ANALYTICAL CHEMISTRY
Knowledge and understanding
- knowledge of the theoretical basis of chemical equilibria in solution
- knowledge of the theoretical/practical bases of the main analytical techniques (chromatographic, elementary)
- knowledge of the performance indices of analytical methods
Ability to apply knowledge and understanding - know how to face and solve problems on chemical equilibria
- be able to compare different techniques for the same purpose also through the analysis of analytical performance indices
- know how to perform analysis
Communication skills
- acquire and know how to use an appropriate chemical vocabulary in relation to the topics covered in the course
- know how to draw up a technical-scientific report
Making judgements
- know how to choose the best procedure to solve problems on chemical equilibria
- know how to choose between different analytical techniques to solve a given analytical problem
- know how to deal with a volumetric analysis by making the appropriate choices from an experimental point of view
Learning skills
- ability to use the study material independently to solve analytical problems